Chemical Structure from Scientific Research

Molecular structure of 3 in crystals of [(TIMMN Mes* )Fe V (=N * )(NCMe)](PF 6 ) 2 (MoF 6 )·5 CH 3 CN depicting the coordination environment of the central pentavalent Fe ion with a typical Fe=N imido bond length of 1.679(3) . All thermal ellipsoids for b and c are shown at 50% probability; counterions, hydrogen atoms and co-crystalized solvent molecules are omitted for clarity, except the amido proton in b and the acetonitrile hydrogens in c .

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