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The effect of a.c. EFs on the conformation of redox moieties : circular dichroism spectra in the Soret region to emphasize the redox-mediated change in haem moieties of free native o.Cyt c , r.Cyt c and bifunctionalized GNP bio-nanoantennae in 10 mM PBS (pH 7.4).theta, molar ellipticity. All samples with identical concentrations (25 ug mL –1 ) were used for spectrum acquisition. Three spectra of each sample were collected and averaged. Insulated, coated steel electrodes were used as a control to demonstrate the occurrence of wireless electrochemistry at the nanoscale.
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