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Subcomponent self-assembly of cages 1-MII and 2-MII (where MII=CoII or FeII), and their hetero-Diels–Alder reactions with 1O2 to produce the modified cages 3-MII, 4-MII, respectively; 3-FeII and 4-FeII were produced as mixtures containing from 1 to 6 endoperoxide moieties per cage.
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