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Cyclic voltammograms of [Cr(L Mes ) 3 ] (red) and [Cr(L Pyr ) 3 ] (purple) in de-aerated dry THF (1 mM) containing 0.1 M n Bu 4 NPF 6 . Inset: Latimer diagram to estimate the potentials for oxidation of Cr(0) in the photoactive 3 MLCT excited state (* E ox (Cr(I/0))) of [Cr(L Mes ) 3 ] and [Cr(L Pyr ) 3 ].
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