Scatter Plot from Scientific Research

Reaction enthalpy for C->D, ΔHC -> D vs. the activation enthalpy, ΔHTS2c, for the methane and for the methanol cycles as in Scheme 1. In (A), literature values reported for Fe0.1Mg1.9(dobdc)234(square), Fe-BTT44(diamond), and Fe-BEA17(empty circle) are also shown. The linear fit for methane (A,r2= 0.99) and methanol (B,r2= 0.83) data are reported as dark gray lines. All the values have been obtained at the UM06-L/def2-TZVP level.

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