Single crystal structures of 6h. Thermal ellipsoids are drawn at the 50% probability level. Some ellipsoids and hydrogen atoms have been removed for clarity. Selected bond lengths [A] and angles [°] for 6h: Ti1C1 2.2044(16), Ti1C2 2.0815(16), C1C2 1.288(2), C4C5 1.211(2), N1B1 1.463(2), N1B2 1.442(2), C1Ti1C2 34.82(6), B1C1C2 165.38(16), C1C2C3 138.62(16), C4B1C1Ti1 87.36(17), and B1C1C2C3 33.1(8).