Chemical Structure from Scientific Research

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Three-dimensional structures of TS1-(S) for the formation of the (S)-product. Bond lengths of the TS geometries are given in A. NCI surfaces are represented as the coloured regions in the figure. Multiple stabilising inter- and intra-molecular NCIs such as hydrogen bonding, - and CH- interactions are observed in the favoured TS TS1-(R) , while the destabilizing steric repulsion between the substrate, nucleophile and catalyst exists in the unfavoured TS TS1-(S) .
#Chemical Structure#Three-Dimensional Structures#TS1-(S)#S-product#Bond Lengths#TS Geometries#NCI Surfaces#Hydrogen Bonding#Pi-Pi Interactions#CH-Pi Interactions#Steric Repulsion#Substrate#Nucleophile#Catalyst
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