Workflow from Scientific Research

(i) Reaction with an aniline to form a hydrogen-bonded adduct. (ii-iv) Reactions with copper(I) chloride, silver(I) triflate and triphenylphosphinegold(I) triflate to yield transition-metal coordination complexes. (v) Reaction with a sulfonic acid to yield a hydroxystibonium salt. (vi) Reaction with acetic acid to yield a cis -hydroxyacetatostiborane. (vii) Reaction with BF 3 to yield a trans -difluorostiborane. (viii) Reaction with phenylsilane to yield stibine 1a . Thermal ellipsoid plots at the 50% probability level are shown next to products; non-polar H atoms are omitted for clarity. Sb, teal; O, red; C, black; H, grey; N, blue; Ag, purple; F, green; S, yellow; Au, gold; P, orange; Cu, mauve.

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