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DAAS with τ 1 = 236 ps, τ 2 = 6.1 ps and τ 3 = 0.5 ps, obtained from femtosecond transient absorption data after excitation at 330 nm and compared with the reduction and oxidation difference spectra obtained from spectroelectrochemical measurements as rough models for LMCT and MLCT excited states neglecting the radical cation and radical anion character of the ligands in these excited states. Inset, transient absorption spectra at the given delay times. ΔOD, change in the optical density.
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