Chemical Structure from Scientific Research

Investigation into substrates favouring the formation of six-membered rings via 1,2-migration, as well as an exploration of alternative alkene substitution patterns. Reactions were performed on 0.125 mmol scale and all yields are isolated. For substrates with additional arene methylation, the direct product is designated with 'a', whereas the arene-methylated product is designated with 'b'. a B1 used. b B2 used. c From free N-H with increased reagent equivalents.

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