Comparative analysis of iron 2p3/2 fs-XAS of LaFeO3 a) ground state (GS) and excited state (ES) spectra at the delay times of 0.2, 1, and 5 ps. The sticks represent crystal field multiplets calculated by CTM4XAS. The GS spectrum was calculated using 10Dq = 1.8 eV. The t2g and eg peaks shift -0.1 and -0.4 eV, respectively. The ES spectra were derived using Equation S5 (Supporting Information), considering alpha = 0.1. The similar ES spectra with different alpha values are plotted in Figure S7 (Supporting Information).
