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A semipreparative-scale biotransformation of 1 catalysed by VEnT1.3 produced optically pure (+)- 1a in essentially quantitative yield (>99% yield, >99% e.e. and 97% isolated yield). Reaction conditions: 0.5 mol% catalyst, 400 M (12 mg) 1 , 5-min irradiation at 405 nm, 4 C.

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