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Population dynamics of TSH simulations from the initially populated S1state together with a global exponential fit of the dynamics. The timescale characterizes the ISC process toward a long-lived triplet species on T1via a transient, short-lived T2population. Population dynamics was averaged over an ensemble of 100 trajectories; all trajectories that violated various energy conservation criteria have been discarded in the analysis (for technical details, see Supporting Information).
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