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Polymerization mechanism: while LiNO3inhibits DOL polymerization, high-enthalpy three-membered cyclic ethers form tertiary oxonium ions even in the presence of LiNO3, which induces and accelerates DOL's ROP (as supported by FiguresS6andS7, Supporting Information) (-R represents CH3(PO), CH2CH3(BO), or CF3(TFEP)).
#Workflow#Illustration#Chemical Structure#Polymerization Mechanism#LiNO3#Cyclic Ethers#Oxonium Ions#Ring-Opening Polymerization
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