Chemical Structure from Scientific Research

Reaction conditions: oxime 1 (0.3 mmol, 1.5 equiv.), acrylamide 2 (0.2 mmol, 1.0 equiv.), [Ir(dF(CF 3 )ppy) 2 (dtbbpy)](PF 6 ) (0.5 mol%), EtOAc (3 mL), N 2 , blue LEDs (440 nm, 10 W), 2 h, fan cooling (35–40 °C). Diastereomeric ratios (dr) were determined by 1 H NMR of the crude reaction mixtures. a 4 h reaction time.

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