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SXRD and (b) NPD patterns of Li6.66[P0.167Si0.5Ge0.167Sb0.167]S5I (Si0.5) with corresponding Rietveld refinement profiles. Black circles are the experimental data, orange (SXRD) and blue (NPD) lines the calculated patterns, and gray lines represent the difference profiles. Vertical tick marks denote the position of expected Bragg reflections [black (argyrodite), light gray (LiI), yellow (Li2S)].
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