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Schematics displaying the lattice mismatch of YVO (given by ( a l − a s )/ a s , where a l and a s are the in-plane lattice parameters of bulk YVO and the substrate, respectively 19 ) (left), Raman spectra of the B 1 g mode at low and high temperatures (centre), integrated intensities of the C -OO phonon (top right) and the G -OO phonon (bottom right) of a YVO film on YAO(110) o substrates. The error bars denote the standard error for the derived ‘peak area’ parameters of the Voigt profiles fitted to the C -OO peaks (blue triangles) and G -OO peaks (pink triangles) ( Methods ). The dashed lines indicate the T OO2/SO2 temperature of the transition from the C -OO/ G -SO ground state to the G -OO/ C -SO intermediate-temperature state.
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