Chemical Structure from Scientific Research

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The structure of TRUMOF-1 is generated by similar components, except that the linear 1,4-bdc linker is replaced by the bent 1,3-bdc isomer (beige angled panels). Clusters are arranged on a face-centred cubic lattice, with each cluster connected to six of its 12 nearest neighbours (we call this topology fcu-6). The connectivity in TRUMOF-1 is aperiodic. Shown in the centre of this panel is a representation of one possible 1 x 1 x 1 approximant. The configurational average of the TRUMOF-1 structure, which is periodic but with partial site occupancies, is represented on the right-hand side.
#Chemical Structure#TRUMOF-1#1,4-bdc Linker#1,3-bdc Isomer#Face-centred Cubic Lattice#fcu-6 Topology#Aperiodic Connectivity#Approximant#Site Occupancies
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