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Meta -selective C( sp 2 )–H functionalization reactions. Applicability of 3 as a precatalyst for meta -selective alkylation was demonstrated using tertiary alkyl halides, an α-bromoester (to give 19b ), Katritzky salt 20 and using tandem-radical cyclization substrate 21 . Blue light, 440 nm; background temperature, 35 °C. SET, single-electron transfer.
#Workflow#Illustration#Chemical Structure#Ruthenium#Functionalization#Precatalyst#Alkylation#Alkyl Halides#Bromoester#Katritzky Salt#Radical Cyclization#Blue Light#Single-Electron Transfer
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