Chemical Structure from Scientific Research

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DOI: 10.1021/jacs.3c09547
Partial view of the X-ray crystal structure of 2OMe down a C2 axis, where dA shows the 5.39 A distance between two CuI centers, dB gives the 3.57 A spacing between the centroids of nearest-neighbor aromatic rings, dC and dD show the 2.71 A C-H···π interactions inferred to stabilize 2OMe, and dE, one of the C-H···F interactions involved in anion binding. Hydrogen atoms are white; fluorine and boron in BF4– are green and pink, respectively.
#Chemical Structure#X-ray Crystal Structure#CuI Centers#Aromatic Rings#C-H···π Interactions#C-H···F Interactions#Anion Binding
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