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DOI: 10.1021/jacs.3c11005
Light-driven progesterone release from trans-1 in a biphasic solvent system. CD3CN and cyclopentane formed two distinct immiscible solvent layers. Slice-selective 1H NMR(42) indicated that the complex of progesterone inside trans-1 dissolved only in CD3CN. Ultraviolet irradiation triggered cage disassembly and concomitant progesterone release. Slice-selective 1H NMR revealed that the released progesterone distributed across both solvent phases.
#Line Plot#Chemical Structure#Light-Driven Release#Progesterone#Biphasic Solvent System#CD3CN#Cyclopentane#Ultraviolet Irradiation#Cage Disassembly
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